Researchers with the U.S. Department of Energy (DOE)’s Lawrence Berkeley National Laboratory (Berkeley Lab) have unveiled a semiconductor nanocrystal coating material capable of controlling heat from the sun while remaining transparent.

BERKELEY, CA – Researchers with the U.S. Department of Energy (DOE)’s Lawrence Berkeley National Laboratory (Berkeley Lab) have unveiled a semiconductor nanocrystal coating material capable of controlling heat from the sun while remaining transparent. Based on electrochromic materials, which use a jolt of electric charge to tint a clear window, this breakthrough technology is the first to selectively control the amount of near-infrared radiation. This radiation, which leads to heating, passes through the film without affecting its visible transmittance. Such a dynamic system could add a critical energy-saving dimension to “smart window” coatings.

“To have a transparent electrochromic material that can change its transmittance in the infrared portion of sunlight is completely unprecedented,” said Delia Milliron, Director of the Inorganic Nanostructures Facility with Berkeley Lab’s Molecular Foundry, who led this research. “What’s more, the coloration efficiency of our material - a figure of merit describing the amount of current needed to make this thing go - is substantially higher than standard electrochromic materials, which means it’s also very efficient.”

Dynamic window coatings could translate into significant energy savings in buildings, which account for more than 40 percent of carbon emissions in the United States. According to studies conducted at the National Renewable Energy Laboratory, smart window coatings could offset the use of climate control and illumination systems by up to 49 percent for air conditioning and 51 percent for lighting.

“Traditional electrochromic windows cannot selectively control the amount of visible and near infrared light that transmits through the film. When operated, these windows can either block both regions of light or let them in simultaneously,” said Guillermo Garcia, a graduate student researcher at the Foundry. “This work represents a stepping stone to the ideal smart window, which would be able to selectively choose which region of sunlight is needed to optimize the temperature inside a building.”

To generate this new coating, the team developed a nanocrystal film of electrically doped indium tin oxide, a transparent semiconductor typically used as a conductive coating for flat-screen TVs. By manipulating the electrons within this semiconducting film, they could tune the collective oscillations of these electrons - a phenomenon called plasmonics - across the near-infrared frequency range.

“Our ability to leverage plasmons in doped semiconductors with a very sensitive switching response in the near-infrared region also brings to mind applications in telecommunications,” Milliron added. “We’ve also brought this synthesis into WANDA, our nanocrystal robot, which means we will be able to provide materials for a wide variety of user projects.”

“This work expands the versatility of electrochromic devices, opening up a variety of new applications in solar and thermal control,” said co-author Thomas Richardson, a Staff Scientist in Berkeley Lab’s Environmental and Energy Technologies Division. “The innovative mechanism with high coloration efficiency offers hope for improved switching ranges and long-term durability.”

Garcia is the lead author and Milliron the corresponding author of a paper reporting this research in the journalNano Letters. The paper is titled “Dynamically modulating the surface plasmon resonance of doped semiconductor nanocrystals.” Co-authoring the paper with Garcia, Milliron and Richardson were Raffaella Buonsanti, Evan Runnerstrom, Rueben Mendelsberg, Anna Llordes and Andre Anders.